Application of Alkyletanolamide Surfactants Based on Nyamplung (Callophylum Inophylum L.) Seed Oil in Cream Base

Dita Auliya Nurfalah, Erin Ryantin Gunawan, Dedy Suhendra, Wahidah Fajrin

Abstract


Cream preparation is cosmetic preparation consisting of aqueous and oil phases that immiscible. Thus, a surfactant with hydrophilic and lipophilic groups is needed to reduce the interfacial tension between the two phases. Petroleum-based surfactants such as Triethanolamine (TEA) are often used in the cosmetic industry. In this study, however, alkyletanolamide surfactant synthesized from vegetable oil was used. Nyamplung, Callophylum inophylum L. (C. inophylum) oil is one of non-commercial vegetable oil that can be used as a substitute to produce surfactants. The aims of this study was to apply surfactant synthesized from C. inophylum oil on the cream preparation and to characterize the alkylethanolamide surfactant by determining the value of hydrophilic-lipophilic balance (HLB). Four different surfactant concentration, 1.5%, 2.0%, 2.5% and 0% were tested as base for the cream preparation. The best surfactant concentration for the cream-based formulation obtained in this study was 2.5% and the surfactant HLB value obtained was 14.40 indicating that alkyletanolamide surfactants can be applied to the oil-in-water (O/W) type of cream base formula.


Keywords


cream; alkylethanolamide surfactant; nyamplung oil

References


Akhtar, N., Khan, B.A., Khan, M.S., Mahmood, T., Khan, H.M.S., Iqbal, M., & Bashir, S. (2011). Formulation Development And Moisturising Effect Of A Topical Cream Of Aloe Vera Extract. World Academy Of Science, Engineering And Technology, 5: 128-136.

Ashish, G. (2014). Determination Of Hydrophilic-Lipophilic Balance Value. International Journal Of Sience And Research, 3(4): 573-575.

Cruz, M., Pinho, S. C., Mota, R., Almeida, M. F., & Dias, J. M. (2018). Enzymatic Esterification Of Acid Oil From Soapstock Obtained In Vegetable Oil Refining: Effect Of Enzyme Concentracion. Renewable Energy, 124(36): 165-171. doi.org/10.1016/j.renene.2017.06.053

Fadhlullaha, M., Nanan, S., Widiyantoa, B., Restiawatya, E., (2015), The Potential of Nyamplung (Calophyllum inophyllum L.) seed oil as Biodiesel Feedstock: Effect of Seed Moisture Content and Particle Size on Oil Yield, 2nd International Conference on Sustainable Energy Engineering and Application, ICSEEA 2014, Energy Procedia, 68: 177 – 185, doi.org/10.1016/j.egypro.2015.03.246

Guzmán E., Ortega, F., Rubio, R.G., (2022), Pickering Emulsions: A Novel Tool for Cosmetic Formulators, Cosmetics 9 (4), 68: 1-14. doi.org/10.3390/cosmetics9040068

Joshi, V., Yashaswini, G., Acharya, A., Bheemachari, Annegowda, H. V., Niraula, B., (2019), Formulation and Evaluation of Semisolid Dosage Forms of an Anti-inflammatory Drug, Biotechnology 9(7): 248. doi.org/10.1007/s13205-019-1769-6

Kartini, Winarjo, B.M., Fitriani, E.W., Islamie, R., (2017), Formulation and pH-Physical Stability Evaluation of Gel and Cream of Plantago major Leaves Extract, Media Pharmaceutica Indonesiana, 1(3): 174-180. doi.org/10.24123/mpi.v1i3.330

Lambers, H., Piessens, S., Bloem, A., Pronk, H., Finkel, P., (2006), Natural Skin Surface pH is on Average below 5, which is Beneficial for its Resident Flora. International Journal Cosmetic Science, 28(5): 359-370. doi.org/10.1111/j.1467-2494.2006.00344.x.

Mantiq, A. (2016 Juli 28). Trietanolamin. Retrieved From Bisakimia: https://bisakimia.com/2016/07/28/trietanolamin

Manzoor, M., Anwar, F., Iqbal, T., & Bhanger, M. I. (2007). Physico-Chemical Characterization Of Moringa Concanensis Seeds Oil. Journal Of Ithe American Oil Chemists Society, 84(5):413-419. doi.org/10.1007/S11746-007-1055-3

Nagtode, V.S., Cardoza, C., Ahmad Yasin, H.H. Mali, S.N., Tambe, S.M., Roy, P., Singh, K., Goel, A., Amin, P.D., Thorat, B.R., Cruz, J.N., Pratap, A.P. (2023), Green Surfactants (Biosurfactants): A Petroleum-Free Substitute for Sustainability Comparison, Applications, Market, and Future Prospects, ACS Omega, 8(13): 11674−11699. doi.org/10.1021/acsomega.3c00591

Nirwana, A.R., Suhendra, D., Gunawan, E.R., (2022), Separation of N-Methylhydroxamic Fatty Acids Based on Ketapang Seed Oil using High Performance Liquid Chromatography, Jurnal Penelitian Pendidikan IPA. Journal of Research in Science Education 8(5): 2329-2334, doi.org/10.29303/jppipa.v8i5.1611

Qadariyah, L., Sahila, S., & Mahfud, M. (2021). The Effect Of Reaction Time And Temperature On The Synthesis Of Methyl Ester Sulfonate Surfactant From Palm Oil As A Feedstock Using Microwave-Assisted Heating. Asean Jurnal Of Chemical Engineering, 21(1): 104-112. doi.org/10.22146/ajche.63786

Rahman I.R. and Herdaningsih, S., (2021), Formulation And Physical Properties Test Of Nano Cream Preparation Purified Extract Of Kenikir Leaf And Tampoi Fruit Peel Extract. Jurnal Ilmiah Farmako Bahari, 12(2): 160-167. doi.org/10.52434/jfb.v12i2.1218

Sari S.W., Djamil R., Faizatun, (2021). Formulation of Blush Preparations by Using Natural Coloring from Red Beetroot Extract (Beta vulgaris L.). Indonesian Journal of Chemistry, 21(4): 860 – 870. doi.org/10.22146/ijc.60414

Sarmah, S., Subrata B.G., Fan X., Annanya A.B., (2020), Characterization and identifcation of the most appropriate nonionic surfactant for enhanced oil recovery. Journal of Petroleum Exploration and Production Technology, 10(1): 115–123. doi.org/10.1007/s13202-019-0682-1

Sharma P.K., Panda A., Parajuli S., Badani Prado R.M., Kundu S., Repka M.A., Ure˜na-Benavides, E., Narasimha Murthy S., (2021), Effect of surfactant on quality and performance attributes of topical semisolids, International Journal of Pharmaceutics 596: 120210. doi.org/10.1016/j.ijpharm.2021.120210

Simone, A. D. (2016). Engineering The Genetic Code Of Eschericha Coli With Methionine Analogues And Bioorthogonal Amino Acids For Protein Immobilization. Von Der Fakultat Ii-Mathematik Und Naturwissenschaften. Berlin: Technischen Universitas Berlin.

Suhendra, D., Gunawan, E. R., Astuti, F., Kurniawati, L. (2020). Separation Of Fatty Acid Ethanolamide Using High Performance Liquid Chromatography. Asian Jurnal of Chemistry, 32(12): 2960-2964. doi.org/10.14233/ajchem.2020.22782

Suhendra, D., Gunawan, E. R., Kusumawati, L. (2019). Synthesis Of Fatty Diethanolamide From Calophyllum Inophylum L Kernel Oill Via Enzymatic Reaction. Rasayan Journal of Chemistry, 12(2): 765-772, doi.org/10.31788/RJC.2019.1225147

Supomo, Apriliana, A., Purnawati, & Ainurisqi T. (2018). Formulation Of Antiacne Cream Dosage Form Containing Mangosteen (Garcinia Mangosteen L.) Pericarp Ethanolic Extract. Indonesian Journal of Pharmaceutical and Clinical Research, 01(01): 37-44. doi.org/10.32734/Idjpcr.V1i1.207.

Tikhonov, A. M. 2010. The Critical Crossover At The N-Hexane-Water Interface. Journal Of Experimental And Theoritical Physics., 110(6): 1055-1057. doi.org/10.1134/s1063776110060142

Widiyati, E., Setiaji B. , Suharto, T.E., Triyono, (2015), The Effect Of Stearic Acid And Triethanolamine (Tea) On Physieal And Chemical Properties Of Cosmetic Emulsion Using Coconut OiI As RawMaterial. Intemational Journal of Applied Chernistry, 11(3): 343-349.


Full Text: PDF

DOI: 10.33751/jf.v13i1.6196 Abstract views : 150 views : 139

Refbacks

  • There are currently no refbacks.